Тип публикации: статья из журнала

Год издания: 2024

Идентификатор DOI: 10.1134/s0036023624601958

Аннотация: Germanates CaYb₂Ge₄O₁₂ and CaLu₂Ge₄O₁₂ have been prepared via firing the solid precursor oxides CaO, Yb₂O₃ (Lu₂O₃), and GeO₂ in air at 1223–1423 K. The X-ray diffraction crystal structures of the prepared germanates have been determined. The high-temperature heat capacity in the range 320–1050 K has been measured by differential scanning calorimetry (DSC). The measured heat capacities are well fitted by the Maier–Kelley equation: <i>C</i>_<i>p</i>(CaYb₂Ge₄O₁₂) = $\left( {{\text{416}}{\text{.4}{\; \pm \;0}}{\text{.40}}} \right) + \left( {{\text{72}}{\text{.67}{\; \pm \;2}}{\text{.30}}} \right){{ \times 1}}{{{\text{0}}}

Журнал: Russian Journal of Inorganic Chemistry

Выпуск журнала: Т. 69, № 9

Номера страниц: 1346-1352

ISSN журнала: 00360236

Место издания: Moscow

Издатель: Pleiades Publishing, Ltd.

• Denisova L.T. (Siberian Federal University)
• Belokopytova D.V. (Siberian Federal University)
• Kargin Yu.F. (Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences)
• Vasil’ev G.V. (Siberian Federal University)
• Belousova N.V. (Siberian Federal University)
• Denisov V.M. (Siberian Federal University)

• Ядро РИНЦ (eLIBRARY.RU)