The impact of surface acid species strength on the cellulose structural changes via hydrolysis over solid acid catalyst

Описание

Тип публикации: статья из журнала

Год издания: 2025

Идентификатор DOI: 10.1007/s00226-025-01681-3

Аннотация: The structural changes of cellulose during a hydrolysis over solid acid catalysts (oxidized carbon Sib450 and sulfonic resin Amberlyst-15) were studied. Cellulose structure alterations were characterized via XRD, FTIR and SEM, among other techniques. It was shown that the hydrolysis of cellulose in an aqueous medium over solid cataПоказать полностьюlysts bearing strong and weak acid species proceeds by different mechanisms, at least under a limited mass-transfer condition. The results are interpreted in terms of the different ability of solid acids to form the electrical double layer—a region near the catalyst surface with a high concentration of hydroxonium ions in an aqueous medium.

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Издание

Журнал: Wood Science and Technology

Выпуск журнала: Т. 59, 4

ISSN журнала: 00437719

Издатель: Springer-Verlag GmbH

Персоны

  • Golubkov Viktor A. (Siberian Federal University)
  • Malyar Yuriy N. (Siberian Federal University)
  • Zaitseva Yulia N. (FRC “Krasnoyarsk Science Center SB RAS”)
  • Sychev Valentin V. (Siberian Federal University)
  • Vorobyev Sergey A. (Siberian Federal University)
  • Taran Oxana P. (Siberian Federal University)

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