Investigation of the Influence of Hydrofluoric Acid and Temperature on the Sintering Processes and Phase Formation in Alumina Nanofiber-based Ceramics

Описание

Тип публикации: статья из журнала

Год издания: 2025

Идентификатор DOI: 10.48084/etasr.9547

Ключевые слова: ceramics, nanofiber, aluminum oxide, hydrofluoric acid, microstructure, compressive strength

Аннотация: <jats:p>This work studies a ceramic material, synthesized from alumina nanofiber via semi-dry pressing with an average diameter of 10 nm and a high aspect ratio (>1000), with Hydrofluoric Acid (HF) used as a mineralizer. The effects of varying firing temperature and HF concentration were systematically investigated. The material waПоказать полностьюs characterized using electron microscopy, X-ray fluorescence analysis, and X-ray phase analysis, while thermodynamic calculations of phase transformations were conducted. Additionally, strength, density, and open porosity were analyzed as functions of the processing parameters. The analysis revealed that an optimal HF concentration of 1% and a firing temperature of 800 °C yield the best physical and mechanical properties. Furthermore, the transition mechanism from the γ-phase to the α-phase under varying HF concentrations and firing temperatures was examined. A linear dependence of the concentration of Fluorine (F) atoms in the ceramic material on the firing temperature was established. The maximum physical and mechanical characteristics include a compressive strength of 49 MPa with a porosity of 46% and a density of 1.47 g/cm³.</jats:p>

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Издание

Журнал: Engineering, Technology and Applied Science Research

Выпуск журнала: Т. 15, 3

Номера страниц: 22792-22801

ISSN журнала: 22414487

Персоны

  • Demianov Alex S. (Siberian Federal University)
  • Dobrosmyslov Sergey S. (Siberian Federal University)
  • Nagibin Gennady E. (Siberian Federal University)
  • Voronin Anton S. (Siberian Federal University)
  • Simunin Mihail M. (Siberian Federal University)
  • Kyylar Airana A. (Federal Research Center "Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences", Russian Academy of Sciences (FRC KSC SB RAS))
  • Molokeev Maksim S. (Far Eastern State Transport University)
  • Fedorova Elena N. (Siberian Federal University)
  • Perkova Marina A. (Siberian Federal University)
  • Nemtsev Ivan V. (Kirensky Institute of Physics, Federal Research Center (KSC SB RAS))
  • Khartov Stanislav V. (Federal Research Center "Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences", Russian Academy of Sciences (FRC KSC SB RAS))

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